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In 2019, International Ocean Discovery Program (IODP) expeditions to offshore West Antarctica recovered deep ocean sediment cores in the outer Amundsen Sea (Exp. 379) and Dove Basin (Exp. 382). These cores are characterized by numerous ice-rafted detritus (IRD) intervals, including dropstone cobbles released by icebergs calved from past glaciers/ice streams that incised the subglacial bedrock of West Antarctica. We selected nine dropstones from latest Miocene through mid-Pliocene sediment from IODP Sites U1532C, U1533B (Exp. 379) and U1536E (Exp. 382), comprising sandstone, diorite, granitoid, basalt, and rhyolite, for petrologic characterization and multi-method geo-thermochronology. Dating methods applied include U-Pb zircon (UPbZ) geochronology, and apatite fission-track (AFT) and (U-Th)/He (AHe) low-temperature thermochronology, to reveal dates and rates of geologic events with bearing on their crustal provenance and source region bedrock thermal history. Comparison to published data reveal dropstones to be of both local and distant origin. Notable discoveries are: 1) From U1536E, a ~1200 Ma [U-PbZ] diorite cobble, with ca. 130 Ma AFT and 65-50 Ma AHe ages that most resembles cratonic crust of Queen Maud Land (East Antarctica). 2) Three granitoid rocks from U1533B with ca. 174-179 Ma (UPbZ) ages. The only known rocks of similar age and lithology in West Antarctica are described in the Whitmore Mountains (WM). AFT ages of 114 Ma, 91 Ma, and 81 Ma may thus provide the first thermochronology data from the WM. 3) A 27±1 Ma (UPbZ) diorite of from U1533B records 25.6 Ma AFT and 10.6 Ma AHe ages, suggesting origins in the western Antarctic Peninsula. 4) Two very similar distinctive green quartz arenite dropstones were recovered from latest Miocene core at U1533B and U1536E, locations separated by 3270 km. Multivariate statistical comparison of their UPbZ age populations with published data indicates a common provenance in the Ellsworth Mountains (Antarctic interior). When placed within geotectonic and paleoclimate context, discoveries from IRD-dropstones promise to advance understanding of crustal and landscape evolution of evolution of glaciated continents, variations in icesheet extent during warm periods, and ocean/atmospheric current circulation. 

Abstract Nanometer‐scale titanomagnetite crystals have been detected in nominally aphyric rhyolite pumice, but whether they are numerous enough to impact bubble nucleation in explosive silicic volcanism was unresolved. This study examines sub‐micron crystals using rock magnetic techniques, Rhyolite‐MELTS modeling, and physical characterization. We analyzed pumice from four eruptions spanning wide ranges in intensity, storage depth, and bubble number density (10¹⁶to 10¹³ m⁻³liquid): 1060 CE Glass Mountain, 1912 CE Novarupta, 232 CE Taupo, and 0.45 Ma Pudahuel. Calculations assuming monospecific assemblages of 10 and 1,000 nm cubic particles yield titanomagnetite number densities of 10²¹to 10¹³m⁻³dense rock equivalent, respectively. In all cases, titanomagnetite is thermodynamically stable at pre‐eruptive storage conditions and magnetic susceptibility (χ_LF) is independent of vesicularity and permeability, indicating that crystals likely formed prior to vesiculation. The existence of nm‐scale Fe‐Ti oxides in four diverse cases suggests that heterogeneous bubble nucleation is a general feature of explosive rhyolite volcanism. 

Data files for rock magnetic data collected on discrete samples at the Institute for Rock Magnetism, University of Minnesota on a Quantum Designs Magnetic Properties System 3 (MPMS3) and Lakeshore Model 8600 Vibrating Sample Magnetometer (VSM). Data include Field Cooled (FC), Zero Field Cooled (ZFC), and Low Temperature Cycling of Room Temperature Saturation Isothermal Remanent Magnetization (LTC-RTSIRM) curves measured on the MPMS and Hysteresis Loops, Direct Current Demagnetization Curves, and Hysteresis Loops collected on the VSM. 

{"Abstract":["Supplementary tables in support of "Antarctic response to orbital forcing during the intensification of extensive bipolar glaciation (1.75-3.30 Ma) from relative paleomagnetic intensity (RPI) stratigraphy of the Dove Basin, Scotia Sea, in Iceberg Alley.""]} 

This dataset archived with the Earthref Magnetics Information Consortium contains low-temperature remanent magnetization data generated at the Institute for Rock Magnetism, University of Minnesota. This dataset accompanies the publication McCartney, K., Hammer, J.E., Shea, T., Brachfeld, S., Giachetti, T., 2024. Investigating the role of nanoscale titanomagnetite in bubble nucleation via novel applications of magnetic analyses (Dataset), Magnetics Information Consortium (MagIC), doi:10.7288/V4/MAGIC/20019. 

This dataset archived with the Magnetics Information Consortium contains rock-magnetic data for rhyolitic pumice and obsidian from Glass Mountain, Medicine Lake, California, USA. Data were generated at Montclair State University and include magnetic susceptibility measured at 976Hz and 3904Hz, magnetic susceptibility vs. temperature, anhysteretic remanent magnetization (ARM), and magnetic hysteresis measurements. This dataset accompanies the publication Brachfeld, S., McCartney, K., Hammer, J.E., Shea, T., Giachetti, T., Evaluating the role of titanomagnetite in bubble nucleation: Rock magnetic detection and characterization of nanolites and ultra-nanolites in rhyolite pumice and obsidian from Glass Mountain, California, Geochemistry Geophysics Geosystems, https://doi.org/10.1029/2023GC011336. 

We document the presence, composition, and number density (TND) of titanomagnetite nanolites and ultra‐nanolites in aphyric rhyolitic pumice, obsidian, and vesicular obsidian from the 1060 CE Glass Mountain volcanic eruption of Medicine Lake Volcano, California, using magnetic methods. Curie temperatures indicate compositions of Fe2.40Ti0.60O4 to Fe3O4. Rock‐magnetic parameters sensitive to domain state, which is dependent on grain volume, indicate a range of particle sizes spanning superparamagnetic (<50–80 nm) to multidomain (>10 μm) particles. Cylindrical cores drilled from the centers of individual pumice clasts display anisotropy of magnetic susceptibility with prolate fabrics, with the highest degree of anisotropy coinciding with the highest vesicularity. Fabrics within a pumice clast require particle alignment within a fluid, and are interpreted to result from the upward transport of magma driven by vesiculation, ensuing bubble growth, and shearing in the conduit. Titanomagnetite number density (TND) is calculated from titanomagnetite volume fraction, which is determined from ferromagnetic susceptibility. TND estimates for monospecific assemblages of 1,000 nm–10 nm cubes predict 10^12 to 10^20 m^−3 of solid material, respectively. TND estimates derived using a power law distribution of grain sizes predict 10^18 to 10^19  m^−3. These ranges agree well with TND determinations of 10^18 to 10^20  m^−3 made by McCartney et al. (2024), and are several orders of magnitude larger than the number density of bubbles in these materials. These observations are consistent with the hypothesis that titanomagnetite crystals already existed in extremely high number‐abundance at the time of magma ascent and bubble nucleation. 

Nucleation of H2O vapor bubbles in magma requires surpassing a chemical supersaturation threshold via decompression. The threshold is minimized in the presence of a nucleation substrate (heterogeneous nucleation, <50 MPa), and maximized when no nucleation substrate is present (homogeneous nucleation, >100 MPa). The existence of explosively erupted aphyric rhyolite magma staged from shallow (<100 MPa) depths represents an apparent paradox that hints at the presence of a cryptic nucleation substrate. In a pair of studies focusing on Glass Mountain eruptive units from Medicine Lake, California, we characterize titanomagnetite nanolites and ultrananolites in pumice, obsidian, and vesicular obsidian (Brachfeld et al., 2024,https://doi.org/10.1029/2023GC011336), calculate titanomagnetite crystal number densities, and compare titanomagnetite abundance with the physical properties of pumice to evaluate hypotheses on the timing of titanomagnetite crystallization. Titanomagnetite crystals with grain sizes of approximately 3–33 nm are identified in pumice samples from the thermal unblocking of low‐temperature thermoremanent magnetization. The titanomagnetite number densities for pumice are 10^18 to 10^20 m^−3, comparable to number densities in pumice and obsidian obtained from room temperature methods (Brachfeld et al., 2024,https://doi.org/10.1029/2023GC011336'>https://doi.org/10.1029/2023GC011336). This range exceeds reported bubble number densities (BND) within the pumice from the same eruptive units (average BND ∼4 × 10^14 m^−3). The similar abundances of nm‐scale titanomagnetite crystals in the effusive and explosive products of the same eruption, together with the lack of correlation between pumice permeability and titanomagnetite content, are consistent with titanomagnetite formation having preceded the bubble formation. Results suggest sub‐micron titanomagnetite crystals are responsible for heterogeneous bubble nucleation in this nominally aphyric rhyolite magma.